Using this set up, you can add a charge to be applied to any orders that are shipping on carrier that isn't marked as a regular carrier (Daily Pickup).
Configuring this page can be done in :
Advanced / Administration / Configure additional Charges - markups, cod charges.
In the field Non-Standard Carrier Charge, enter the desired charge to be applied to all orders that don't match a standard/daily pick up carrier.
Carriers can be mark as standard or not, in the manage Carriers screen.
Advanced > Administration > DC Settings - Carrier
Daily Pickup unchecked indicates it is non-standard and vice versa.